 |
DTIC ADA197086: Electron-Transfer Reactions of Organometallic and C... |
 |
by Defense Technical Information Center |
 |
Thumbnail |
|
Download |
 |
Web page |
|
|
|
The kinetics of gas-phase electron transfer reactions for |
|
a variety of metal-containing reactants have been studied |
|
by using Fourier transform ion cyclotron resonance mass |
|
spectrometry. Classes of ion/molecule processes studied |
|
include both self-exchange (thermoneutral) and exoergic |
|
cross reactions. The molecules investigated include |
|
metallocenes and octahedral coordination complexes of the |
|
transition elements. In a few cases, direct comparisons |
|
of condensed-phase and gas-phase reactivities can be |
|
made. The experiments with octahedral coordination |
|
complexes are the first studies of Werner-type metal |
|
complexes in electron-transfer reactions in the gas |
|
phase. Simple theoretical mechanical approaches are used |
|
to rationalize the dependence of the overall rates of |
|
these reactions on the molecular properties of the |
|
reactants. In particular, the role of Franck-Condon |
|
factors in charge-transfer reactions is examined, and |
|
theoretically estimated factors are compared to |
|
experiment for a typical metallocene, ferrocene. |
|
|
|
Date Published: 2018-02-19 20:11:59 |
|
Identifier: DTIC_ADA197086 |
|
Item Size: 15689617 |
|
Language: english |
|
Media Type: texts |
|
|
|
# Topics |
|
DTIC Archive; Sharpe, Paul; FLORIDA U... |
|
|
|
# Collections |
|
dticarchive |
|
additional_collections |
|
|
|
# Uploaded by |
|
@chris85 |
|
|
|
# Similar Items |
|
View similar items |
|
|
|
PHAROS |
|
