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=                              Nonmetal                              =
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                            Introduction
======================================================================
|A periodic table extract
alt=A grid with 7 rows labeled periods "1" to "7" and 10 columns
labeled as groups "1", "2", "3-11", and "12" to "18".   ¶ Most cells
represent one chemical element and are labeled with its 1 or 2 letter
symbol in a large font above its name. Cells in column 3 (labeled
"3-11") represent a series of elements and are labeled with the first
and last element's symbol.      ¶ Row 1 has cells in the first and last
columns, with an empty gap between. Rows 2-3 have 8 cells, with a gap
between the first 2 and last 6 columns. Rows 4-7 have cells in all 10
columns.        ¶ A bold falling staircase line separates the rightmost
6/5/4/3/2/1 cells in rows 2-7.  ¶ 17 cells above and right of the
staircase are tan-colored: both cells row 1 and all cells to its right
except the first one.   ¶ 9 cells along the staircase are specially
colored: gray in rows 2-5 and brown in rows 6-7: the first cell after
it in rows 2-7 and first cell before in rows 4/5/7.     ¶ The rest of the
cells have light gray letters on a white background.
|always/usually considered nonmetals
|metalloids, sometimes considered nonmetals
|status as nonmetal or metal unconfirmed

In the context of the periodic table, a nonmetal is a chemical element
that mostly lacks distinctive metallic properties. They range from
colorless gases like hydrogen to shiny crystals like iodine.
Physically, they are usually lighter (less dense) than elements that
form metals and are often poor conductors of heat and electricity.
Chemically, nonmetals have relatively high electronegativity or
usually attract electrons in a chemical bond with another element, and
their oxides tend to be acidic.

Seventeen elements are widely recognized as nonmetals. Additionally,
some or all of six borderline elements (metalloids) are sometimes
counted as nonmetals.

The two lightest nonmetals, hydrogen and helium, together account for
about 98% of the mass of the observable universe. Five nonmetallic
elements--hydrogen, carbon, nitrogen, oxygen, and silicon--form the
bulk of Earth’s atmosphere, biosphere, crust and oceans, although
metallic elements are believed to be slightly more than half of the
overall composition of the Earth.

Chemical compounds and alloys involving multiple elements including
nonmetals are widespread. Industrial uses of nonmetals as the dominant
component include in electronics, combustion, lubrication and
machining.

Most nonmetallic elements were identified in the 18th and 19th
centuries. While a distinction between metals and other minerals had
existed since antiquity, a classification of chemical elements as
metallic or nonmetallic emerged only in the late 18th century. Since
then about twenty properties have been suggested as criteria for
distinguishing nonmetals from metals. In contemporary research usage
it is common to use a distinction between metal and not-a-metal based
upon the electronic structure of the solids; the elements carbon,
arsenic and antimony are then semimetals, a subclass of metals. The
rest of the nonmetallic elements are insulators, some of which such as
silicon and germanium can readily accommodate dopants that change the
electrical conductivity leading to semiconducting behavior.


                 Definition and applicable elements
======================================================================
:'Unless otherwise noted, this article describes the stable form of an
element at standard temperature and pressure (STP).'

Nonmetallic chemical elements are often broadly defined as those that
mostly lack properties commonly associated with metals--namely
shininess, pliability, good thermal and electrical conductivity (due
to their  band structure), and a general capacity to form basic
oxides. There is no widely accepted precise definition in terms of
these properties; any list of nonmetals is open to debate and
revision.

Fourteen elements are almost always recognized as nonmetals:




Three more are commonly classed as nonmetals, but some sources list
them as "metalloids", a term which refers to elements intermediate
between metals and nonmetals:


One or more of the six elements most commonly recognized as metalloids
are sometimes instead counted as nonmetals:


About 15-20% of the 118 known elements are thus classified as
nonmetals.


Physical
==========
Nonmetals vary greatly in appearance, being colorless, colored or
shiny.
For the colorless nonmetals (hydrogen, nitrogen, oxygen, and the noble
gases), no absorption of light happens in the visible part of the
spectrum, and all visible light is transmitted.
The colored nonmetals (sulfur, fluorine, chlorine, bromine) absorb
some colors (wavelengths) and transmit the complementary or opposite
colors. For example, chlorine's "familiar yellow-green colour ... is
due to a broad region of absorption in the violet and blue regions of
the spectrum". The shininess of boron, graphite (carbon), silicon,
black phosphorus, germanium, arsenic, selenium, antimony, tellurium,
and iodine is a result of the electrons reflecting incoming visible
light.

About half of nonmetallic elements are gases under standard
temperature and pressure; most of the rest are solids. Bromine, the
only liquid, is usually topped by a layer of its reddish-brown fumes.
The gaseous and liquid nonmetals have very low densities, melting and
boiling points, and are poor conductors of heat and electricity. The
solid nonmetals have low densities and low mechanical strength (being
either hard and brittle, or soft and crumbly), and a wide range of
electrical conductivity.

This diversity stems from variability in crystallographic structures
and bonding arrangements. Covalent nonmetals existing as discrete
atoms like xenon, or as small molecules, such as oxygen, sulfur, and
bromine, have low melting and boiling points; many are gases at room
temperature, as they are held together by weak London dispersion
forces acting between their atoms or molecules, although the molecules
themselves have strong covalent bonds. In contrast, nonmetals that
form extended structures, such as long chains of selenium atoms,
sheets of carbon atoms in graphite, or three-dimensional lattices of
silicon atoms have higher melting and boiling points, and are all
solids. Nonmetals closer to the left or bottom of the periodic table
(and so closer to the metals) often have metallic interactions between
their molecules, chains, or layers; this occurs in boron, carbon,
phosphorus, arsenic, selenium, antimony, tellurium and iodine.

Some general physical differences between elemental metals and
nonmetals
Aspect !! Metals !! Nonmetals
|Appearance and form    |Shiny if freshly prepared or fractured; few
colored; all but one solid      |Shiny, colored or transparent; all but one
solid or gaseous
|Density        Often higher    Often lower
Plasticity      Mostly malleable and ductile    Often brittle solids
Electrical conductivity Good    Poor to good
Electronic structure    Metal or semimetalic    Semimetal, semiconductor,
or insulator
Covalently bonded nonmetals often share only the electrons required to
achieve a noble gas electron configuration. For example, nitrogen
forms diatomic molecules featuring a triple bonds between each atom,
both of which thereby attain the configuration of the noble gas neon.
In contrast antimony has buckled layers in which each antimony atom is
singly bonded with three other nearby atoms.

Good electrical conductivity occurs when there is metallic bonding,
however the electrons in some nonmetals are not metallic. Good
electrical and thermal conductivity associated with metallic electrons
is seen in carbon (as graphite, along its planes), arsenic, and
antimony. Good thermal conductivity occurs in boron, silicon,
phosphorus, and germanium; such conductivity is transmitted though
vibrations of the crystalline lattices (phonons of these elements.
Moderate electrical conductivity is observed in the semiconductors
boron, silicon, phosphorus, germanium, selenium, tellurium, and
iodine.

Many of the nonmetallic elements are hard and brittle, where
dislocations cannot readily move so they tend to undergo brittle
fracture rather than deforming. Some do deform such as white
phosphorus (soft as wax, pliable and can be cut with a knife at room
temperature), plastic sulfur, and selenium which can be drawn into
wires from its molten state. Graphite is a standard solid lubricant
where dislocations move very easily in the basal planes.


Allotropes
============
Over half of the nonmetallic elements exhibit a range of less stable
allotropic forms, each with distinct physical properties. For example,
carbon, the most stable form of which is graphite, can manifest as
diamond, buckminsterfullerene, amorphous and paracrystalline
variations. Allotropes also occur for nitrogen, oxygen, phosphorus,
sulfur, selenium and iodine.


Chemical
==========
Some general chemistry-based differences between metals and nonmetals
colspan=2 | Aspect !! Metals !! Nonmetals
colspan=2 |Reactivity   Wide range: very reactive to noble
rowspan =2 | Oxides      lower  Basic   rowspan =2 | Acidic; never basic
higher   Increasingly acidic
colspan=2 |Compounds with metals        Alloys  Covalent or Ionic
colspan=2 | Ionization energy   Low to high     Moderate to very high
colspan=2 | Electronegativity   Low to high     Moderate to very high
Nonmetals have relatively high values of electronegativity, and their
oxides are usually acidic. Exceptions may occur if a nonmetal is not
very electronegative, or if its oxidation state is low, or both. These
non-acidic oxides of nonmetals may be amphoteric (like water, H2O) or
neutral (like nitrous oxide, N2O), but never basic.

They tend to gain electrons during chemical reactions, in contrast to
metallic elements which tend to donate electrons. This behavior is
related to the stability of electron configurations in the noble
gases, which have complete outer shells, empirically described by the
duet and octet rules of thumb, more correctly explained in terms of
valence bond theory.

The chemical differences between metals and nonmetals stem from
variations in how strongly atoms attract and retain electrons. Across
a period of the periodic table, the nuclear charge increases as more
protons are added to the nucleus. However, because the number of inner
electron shells remains constant, the effective nuclear charge
experienced by the outermost electrons also increases, pulling them
closer to the nucleus. This leads to a corresponding reduction in
atomic radius, and a greater tendency of these elements to gain
electrons during chemical reactions, forming negatively charged ions.
Nonmetals, which occupy the right-hand side of the periodic table,
exemplify this behavior.

Nonmetals typically exhibit higher ionization energies, electron
affinities, and standard electrode potentials than metals. The higher
these values are (including electronegativity) the more nonmetallic
the element tends to be. For example, the chemically very active
nonmetals fluorine, chlorine, bromine, and iodine have an average
electronegativity of 3.19--a figure higher than that of any metallic
element.

The number of compounds formed by nonmetals is vast. The first 10
places in a "top 20" table of elements most frequently encountered in
895,501,834 compounds, as listed in the Chemical Abstracts Service
register for November 2, 2021, were occupied by nonmetals. Hydrogen,
carbon, oxygen, and nitrogen collectively appeared in most (80%) of
compounds. Silicon, a metalloid, ranked 11th. The highest-rated metal,
with an occurrence frequency of 0.14%, was iron, in 12th place.


Complications
===============
Adding complexity to the chemistry of the nonmetals are anomalies
occurring in the first row of each periodic table block; non-uniform
periodic trends; higher oxidation states; multiple bond formation; and
property overlaps with metals.


First row anomaly
===================
alt=A table with seven rows and ten columns. Rows are labeled on the
left with a period number from 1 through 7. Columns are labeled on the
bottom with a group number. Most cells represent a single chemical
element and have two lines of information: the element's symbol on the
top and its atomic number on the bottom. The table as a whole is
divided into four rectangular areas separated from each other by
narrow gaps. The first rectangle fills all seven rows of the first two
columns. The rectangle is labeled "s-block" at the top and its two
columns are labeled with group numbers "(1)" and "(2)" on the bottom.
The cells in the first row - hydrogen and helium, with symbols H and
He and atomic numbers 1 and 2 respectively - are both shaded red. The
second rectangle fills the bottom two rows (periods 6 and 7) of the
third column. Just above these cells is the label "f-block"; there is
no group label on the bottom. The topmost cell - labeled "La-Yb" for
elements 57-70 - is shaded green. The third rectangle fills the bottom
four rows (periods 4 through 7) of the fourth column. Just above these
cells is the label "d-block"; at the bottom is the label "(3-12)" for
the group numbers of these elements. The topmost cell - labeled
"Sc-Zn" for elements 21-30 - is shaded blue. The fourth and last
rectangle fills the bottom six rows (periods 2 through 7) of the last
six columns. Just above these cells is the label "p-block"; at the
bottom are labels "(13)" through "(18) for the group numbers of these
elements. The cells in the topmost row - for the elements boron (B,5),
carbon (C,6), nitrogen (N,7), oxygen (O,8), fluorine (Fl,9), and neon
(Ne,10) - are shaded yellow. Bold lines encircle the cells of the
nonmetals - the top two cells on the left and 21 cells in the upper
right of the table.
| **Condensed periodic table highlighting the first row of each
block:    and **
| colspan=1 | **Period**
| colspan=2 | ****
colspan=1       colspan=1       colspan=6
| **1**
| colspan=6 |  **p-block**
|s-block}};" | H  1     |s-block}};" | He 2
| **2**
Li 3    Be 4    |p-block}};" | B  5     |p-block}};" | C  6     |p-block}};" | N  7
|p-block}};" | O  8     |p-block}};" | F  9     |p-block}};" | Ne 10
| **3**
|  ****
Na 11   Mg 12   Al 13   Si 14   P  15   S  16   Cl 17   Ar 18
| **4**
K  19   Ca 20   |d-block}};" | Sc-Zn 21-30      Ga 31   Ge 32   As 33   Se 34   Br 35
Kr 36
| **5**
|  ****
Rb 37   Sr 38   Y-Cd 39-48      In 49   Sn 50   Sb 51   Te 52   I  53   Xe 54
| **6**
Cs 55   Ba 56   |f-block}};" | La-Yb 57-70      'Lu-Hg 71-80'   Tl 81   Pb 82   Bi
83      Po 84   At 85   Rn 86
| **7**
Fr 87   Ra 88   Ac-No 89-102    Lr-Cn 103-112   Nh 113  Fl 114  Mc 115  Lv 116  Ts
117     Og 118
'Group' '(1)'   '(2)'   '(3-12)'        '(13)'  '(14)'  '(15)'  '(16)'  '(17)'
'(18)'
| The first-row anomaly strength by block is **s** >> **p**
> **d** > **f**.
Starting with hydrogen, the first row anomaly primarily arises from
the electron configurations of the elements concerned. Hydrogen is
notable for its diverse bonding behaviors. It most commonly forms
covalent bonds, but it can also lose its single electron in an aqueous
solution, leaving behind a bare proton with high polarizing power.
Consequently, this proton can attach itself to the lone electron pair
of an oxygen atom in a water molecule, laying the foundation for
acid-base chemistry. Moreover, a hydrogen atom in a molecule can form
a second, albeit weaker, bond with an atom or group of atoms in
another molecule. Such bonding, "helps give snowflakes their hexagonal
symmetry, binds DNA into a double helix; shapes the three-dimensional
forms of proteins; and even raises water's boiling point high enough
to make a decent cup of tea."

Hydrogen and helium, as well as boron through neon, have small atomic
radii. The ionization energies and electronegativities among these
elements are higher than the periodic trends would otherwise suggest.

While it would normally be expected, on electron configuration
consistency grounds, that hydrogen and helium would be placed atop the
s-block elements, the significant first row anomaly shown by these two
elements justifies alternative placements. Hydrogen is occasionally
positioned above fluorine, in group 17, rather than above lithium in
group 1. Helium is almost always placed above neon, in group 18,
rather than above beryllium in group 2.


Secondary periodicity
=======================
An alternation in certain periodic trends, sometimes referred to as
secondary periodicity, becomes evident when descending groups 13 to
15, and to a lesser extent, groups 16 and 17. Immediately after the
first row of d-block metals, from scandium to zinc, the 3d electrons
in the p-block elements--specifically, gallium (a metal), germanium,
arsenic, selenium, and bromine--prove less effective at shielding the
increasing positive nuclear charge.

The Soviet chemist  gives two more tangible examples:
:"The toxicity of some arsenic compounds, and the absence of this
property in analogous compounds of phosphorus [P] and antimony [Sb];
and the ability of selenic acid [] to bring metallic gold [Au] into
solution, and the absence of this property in sulfuric [] and []
acids."


Higher oxidation states
=========================
:'Roman numerals such as III, V and VIII denote oxidation states'

Some nonmetallic elements exhibit oxidation states that deviate from
those predicted by the octet rule, which typically results in an
oxidation state of -3 in group 15, -2 in group 16, -1 in group 17, and
0 in group 18. Examples include ammonia NH3, hydrogen sulfide H2S,
hydrogen fluoride HF, and elemental xenon Xe. Meanwhile, the maximum
possible oxidation state increases from +5 in group 15, to +8 in group
18. The +5 oxidation state is observable from period 2 onward, in
compounds such as nitric acid HN(V)O3 and phosphorus pentafluoride
PCl5. Higher oxidation states in later groups emerge from period 3
onwards, as seen in sulfur hexafluoride SF6, iodine heptafluoride IF7,
and xenon(VIII) tetroxide XeO4. For heavier nonmetals, their larger
atomic radii and lower electronegativity values enable the formation
of compounds with higher oxidation numbers, supporting higher bulk
coordination numbers.


Property overlaps
===================
While certain elements have traditionally been classified as nonmetals
and others as metals, some overlapping of properties occurs. Writing
early in the twentieth century, by which time the era of modern
chemistry had been well-established (although not as yet more precise
quantum chemistry) Humphrey observed that:
:... these two groups, however, are not marked off perfectly sharply
from each other; some nonmetals resemble metals in certain of their
properties, and some metals approximate in some ways to the
non-metals.

Boron (here in its less stable amorphous form) shares some
similarities with metals
Examples of metal-like properties occurring in nonmetallic elements
include:
* Silicon has an electronegativity (1.9) comparable with metals such
as cobalt (1.88), copper (1.9), nickel (1.91) and silver (1.93);
* The electrical conductivity of graphite exceeds that of some metals;
* Selenium can be drawn into a wire;
* Radon is the most metallic of the noble gases and begins to show
some cationic behavior, which is unusual for a nonmetal; and
* In extreme conditions, just over half of nonmetallic elements can
form homopolyatomic cations.

Examples of nonmetal-like properties occurring in metals are:
*Tungsten displays some nonmetallic properties, sometimes being
brittle, having a high electronegativity, and forming only anions in
aqueous solution, and predominately acidic oxides.
*Gold, the "king of metals" has the highest electrode potential among
metals, suggesting a preference for gaining rather than losing
electrons. Gold's ionization energy is one of the highest among
metals, and its electron affinity and electronegativity are high, with
the latter exceeding that of some nonmetals. It forms the Au- auride
anion and exhibits a tendency to bond to itself, behaviors which are
unexpected for metals. In aurides (MAu, where M = Li-Cs), gold's
behavior is similar to that of a halogen. The reason for this is that
gold has a large enough nuclear potential that the electrons have to
be considered with relativistic effects included, which changes some
of the properties.

A relatively recent development involves certain compounds of heavier
p-block elements, such as silicon, phosphorus, germanium, arsenic and
antimony, exhibiting behaviors typically associated with transition
metal complexes. This is linked to a small energy gap between their
filled and empty molecular orbitals, which are the regions in a
molecule where electrons reside and where they can be available for
chemical reactions. In such compounds, this allows for unusual
reactivity with small molecules like hydrogen (H2), ammonia (NH3), and
ethylene (C2H4), a characteristic previously observed primarily in
transition metal compounds. These reactions may open new avenues in
catalytic applications.


                      Types {{anchor|Classes}}
======================================================================
Nonmetal classification schemes vary widely, with some accommodating
as few as two subtypes and others up to seven. For example, the
periodic table in the Encyclopaedia Britannica recognizes noble gases,
halogens, and other nonmetals, and splits the elements commonly
recognized as metalloids between "other metals" and "other nonmetals".
On the other hand, seven of twelve color categories on the Royal
Society of Chemistry periodic table include nonmetals.

|  **Group** (1, 13−18)
|  **Period**
13      14      15      16      1/17    18
| **1**
H       He
| **2**
B       C       N       O       F       Ne
| **3**
Si      P       S       Cl      Ar
| **4**
Ge      As      Se      Br      Kr
| **5**
Sb      Te      I       Xe
| **6**
Rn

|}
Starting on the right side of the periodic table, three types of
nonmetals can be recognized:


the inert noble gases--helium, neon, argon, krypton, xenon, radon;


the reactive halogen nonmetals--fluorine, chlorine, bromine, iodine;
and


the mixed reactivity "unclassified nonmetals", a set with no widely
used collective name--hydrogen, carbon, nitrogen, oxygen, phosphorus,
sulfur, selenium. The descriptive phrase 'unclassified nonmetals' is
used here for convenience.

The elements in a fourth set are sometimes recognized as nonmetals:


the generally unreactive  metalloids, sometimes considered a third
category distinct from metals and nonmetals--boron, silicon,
germanium, arsenic, antimony, tellurium.

The boundaries between these types are not sharp. Carbon, phosphorus,
selenium, and iodine border the metalloids and show some metallic
character, as does hydrogen.

The greatest discrepancy between authors occurs in metalloid "frontier
territory". Some consider metalloids distinct from both metals and
nonmetals, while others classify them as nonmetals. Some categorize
certain metalloids as metals (e.g., arsenic and antimony due to their
similarities to heavy metals). Metalloids resemble the elements
universally considered "nonmetals" in having relatively low densities,
high electronegativity, and similar chemical behavior.


Noble gases
=============
Six nonmetals are classified as noble gases: helium, neon, argon,
krypton, xenon, and the radioactive radon. In conventional periodic
tables they occupy the rightmost column. They are called 'noble' gases
due to their exceptionally low chemical reactivity.

These elements exhibit similar properties, being colorlessness,
odorless, and nonflammable. Due to their closed outer electron shells,
noble gases possess weak interatomic forces of attraction, leading to
exceptionally low melting and boiling points.

Chemically, the noble gases exhibit relatively high ionization
energies, negligible or negative electron affinities, and high to very
high electronegativities. The number of compounds formed by noble
gases is in the hundreds and continues to expand, with most of these
compounds involving the combination of oxygen or fluorine with either
krypton, xenon, or radon.


Halogen nonmetals
===================
Chemically, the halogen nonmetals have high ionization energies,
electron affinities, and electronegativity values, and are relatively
strong oxidizing agents. All four elements tend to form primarily
ionic compounds with metals, in contrast to the remaining nonmetals
(except for oxygen) which tend to form primarily covalent compounds
with metals.


Unclassified nonmetals
========================
Hydrogen behaves in some respects like a metallic element and in
others like a nonmetal. Like a metallic element it can, for example,
form a solvated cation in aqueous solution; it can substitute for
alkali metals in compounds such as the chlorides (NaCl cf. HCl) and
nitrates (KNO3 cf. HNO3), and in certain alkali metal complexes as a
nonmetal. It attains this configuration by forming a covalent or ionic
bond or by bonding as an ion to a lone pair of electrons.

Some or all of these nonmetals share several properties. Being
generally less reactive than the halogens, most of them can occur
naturally in the environment. Collectively, their physical and
chemical characteristics can be described as "moderately
non-metallic". When combined with metals, the unclassified nonmetals
can form interstitial or refractory compounds. They also exhibit a
tendency to bond to themselves, particularly in solid compounds.
Additionally, diagonal periodic table relationships among these
nonmetals mirror similar relationships among the metalloids.


Abundance
===========
Approximate composition
| **Universe**
75% *hydrogen    23% *helium      1% *oxygen
| **Atmosphere**
78% *nitrogen    21% *oxygen     0.5% *argon
| **Hydrosphere**
86% *oxygen      11% *hydrogen    2% *chlorine
| **Biomass**
63% *oxygen      20% *carbon     10% *hydrogen
| **Crust**
46% *oxygen      27% *silicon    8% aluminium
| **Earth**
32% iron         30% *oxygen     14% magnesium
The abundance of elements in the universe results from nuclear physics
processes like nucleosynthesis and radioactive decay.

The volatile noble gas nonmetal elements are less abundant in the
atmosphere than expected based upon their overall abundance due to
cosmic nucleosynthesis. Mechanisms to explain this difference is an
important aspect of planetary science. The element  is unexpectedly
depleted, and a possible explanation comes from theoretical models of
the high pressures in the Earth's core suggesting that there may be
around 1013 tons of xenon in the form of stable XeFe3 and XeNi3
intermetallic compounds.

Five nonmetals--hydrogen, carbon, nitrogen, oxygen, and silicon--form
the bulk of the directly observable structure of the Earth: about 73%
of the crust, 93% of the biomass, 96% of the hydrosphere, and over 99%
of the atmosphere, as shown in the accompanying table. Silicon and
oxygen form stable tetrahedral structures, known as silicates. Here,
"the powerful bond that unites the oxygen and silicon ions is the
cement that holds the Earth's crust together." However, they make up
less than 50% of the total weight of the earth.

In the biomass, the relative abundance of the first four nonmetals
(and phosphorus, sulfur, and selenium marginally) is attributed to a
combination of relatively small atomic size, and sufficient spare
electrons. These two properties enable them to bind to one another and
"some other elements, to produce a molecular soup sufficient to build
a self-replicating system."


Extraction
============
Nine of the 23 nonmetallic elements are gases, or form compounds that
are gases, and are extracted from natural gas or liquid air, including
hydrogen, nitrogen, oxygen, sulfur, and most of the noble gases. For
example, nitrogen and oxygen are extracted from liquid air through
fractional distillation and  sulfur from the hydrogen sulfide in
natural gas by reacting it with oxygen to yield water and sulfur.
Three nonmetals are extracted from seawater; the rest of the nonmetals
- and almost all metals - from mining solid ores.

|  **Group** (1, 13−18)
|  **Period**
13      14      15      16      1/17    18
| **1**
H        He
| **2**
|B      |C      |N      |O      |F      |Ne
| **3**
|Si     |P      |S      |Cl     |Ar
| **4**
|Ge     |As     |Se     |Br     |Kr
| **5**
|Sb     |Te     |I      |Xe
| **6**
|Rn
are extracted from these sources:

;from natural gas components: hydrogen (methane), helium, and sulfur
(hydrogen sulfide)

;from liquefied air: nitrogen, oxygen, neon, argon, krypton, and xenon

;from seawater brine: chlorine, bromine, and iodine

;from solid ores: boron (borates), carbon (natural graphite), silicon
(silica), phosphorus (phosphates), iodine (sodium iodate), radon
(uranium ore decay product), fluorine (fluorite);  and germanium,
arsenic, selenium, antimony, and tellurium (from their sulfides).


Uses
======
Nonmetallic elements are present in combination with other elements in
almost everything around us, from water to plastics and within
metallic alloys. There are some specific uses of the elements
themselves, although these are less common; extensive details can be
found in the specific pages of the relevant elements. A few examples
are:

# Hydrogen can be used in fuel cells, and is being explored for a
possible future low-carbon hydrogen economy.
# Carbon has many uses, ranging from decorative applications of
diamond jewelry to diamond in cutting blades and graphite as a solid
lubricant.
# Liquid nitrogen is extensively used as a coolant.
# Oxygen is a critical component of the air we breath. (While nitrogen
is also present, it is less used from the air, mainly by certain
bacteria.) Oxygen gas and liquid is also heavily used for combustion
in welding and cutting torches and as a component of rocket fuels.
# Silicon is the most widely used semiconductor. While ultra-pure
silicon is an insulator, by selectively adding electronic dopants it
can be used as a semiconductor where the chemical potential of the
electrons can be manipulated, this being exploited in a wide range of
electronic devices.
# The noble gases have a range of applications, including liquid
helium for cryogenic cooling, and argon to in gaseous fire suppression
to -damp fires around sensitive electrical equipment where water
cannot be used.
# Radon is a potentially hazardous indoor pollutant.


Background
============
Medieval chemical philosophers focused on metals, rarely investigating
nonmetallic minerals.


Organization of elements by types
===================================
In the late 1700s, French chemist Antoine Lavoisier published the
first modern list of chemical elements in his revolutionary 1789
'Traité élémentaire de chimie'. The 33 elements known to Lavoisier
were categorized into four distinct groups, including gases, metallic
substances, nonmetallic substances that form acids when oxidized, and
earths (heat-resistant oxides). Lavoisier's work gained widespread
recognition and was republished in twenty-three editions across six
languages within its first seventeen years, significantly advancing
the understanding of chemistry in Europe and America.  Lavoisier's
chemistry was "dualistic",: "salts" were combinations of "acid" and
"base"; acids where combinations of oxygen and metals while bases
where combinations of oxygen and nonmetals. This view prevailed
despite increasing evidence that chemicals like chlorine and ammonia
contained no oxygen, in large part due the vigious if sometimes
misguided defense by the Swedish chemist Berzelius.

In 1802 the term "metalloids" was introduced for elements with the
physical properties of metals but the chemical properties of
non-metals. In 1811 Berzelius used the term "metalloids" to describe
all nonmetallic elements, noting their ability to form negatively
charged ions with oxygen in aqueous solutions. Drawing on this, in
1864 the "Manual of Metalloids" divided all elements into either
metals or metalloids, with the latter group including elements now
called nonmetals.  Reviews of the book indicated that the term
"metalloids" was still endorsed by leading authorities, but there were
reservations about its appropriateness. While Berzelius' terminology
gained significant acceptance, it later faced criticism from some who
found it counterintuitive, misapplied, or even invalid.  The idea of
designating elements like arsenic as metalloids had been considered.
The use of the term "metalloids" persisted in France as textbooks of
chemistry appeared in the 1800s. During this period, "metals" as a
chemical category were characterized by a single property, their
affinity for oxygen, while "metalloids" were organized by comparison
of many characteristic analogous to the approach of naturalists.


Development of types
======================
In 1844, , a French doctor, pharmacist, and chemist, established a
basic taxonomy of nonmetals to aid in their study. He wrote:

:They will be divided into four groups or sections, as in the
following:
::Organogens--oxygen, nitrogen, hydrogen, carbon
::Sulphuroids--sulfur, selenium, phosphorus
::Chloroides--fluorine, chlorine, bromine, iodine
::Boroids--boron, silicon.

Dupasquier's quartet parallels the modern nonmetal types. The
organogens and sulphuroids are akin to the unclassified nonmetals. The
chloroides were later called halogens. The boroids eventually evolved
into the metalloids, with this classification beginning from as early
as 1864. The then unknown noble gases were recognized as a distinct
nonmetal group after being discovered in the late 1800s. This taxonomy
was noted as a "natural classification" of the substance considering
all aspects rather than an single characteristic like oxygen affinity.
It was a significant departure from other contemporary
classifications, since it grouped together oxygen, nitrogen, hydrogen,
and carbon.

In 1828 and 1859, the French chemist Dumas classified nonmetals as (1)
hydrogen; (2) fluorine to iodine; (3) oxygen to sulfur; (4) nitrogen
to arsenic; and (5) carbon, boron and silicon, thereby anticipating
the vertical groupings of Mendeleev's 1871 periodic table. Dumas' five
classes fall into modern groups 1, 17, 16, 15, and 14 to
13 respectively.


Nonmetals as terminology
==========================
By as early as 1866, some authors began preferring the term "nonmetal"
over "metalloid" to describe nonmetallic elements. In 1875, Kemshead
observed that elements were categorized into two groups: non-metals
(or metalloids) and metals. He noted that the term "non-metal",
despite its compound nature, was more precise and had become
universally accepted as the nomenclature of choice.


Structure, quantum mechanics and band structure
=================================================
The early terminologies were empirical categorizations based upon
observables. As the 20th century started there were significant
changes in understanding. The first was due to methods, mainly x-ray
crystallography, for determining how atoms are arranged in the various
materials. As early as 1784 René Just Haüy discovered that every face
of a crystal could be described by simple stacking patterns of blocks
of the same shape and size (law of decrements).  Haüy's study led to
the idea that crystals are a regular three-dimensional array (a
Bravais lattice) of atoms and molecules, with a single unit cell
repeated indefinitely, along with other developments in the early days
of physical crystallography. After Max von Laue demonstrated in 1912
that x-rays diffract, fairly quickly William Lawrence Bragg and his
father William Henry Bragg were able to solve previously unknown
structures. Building on this, it became clear that most of the simple
elemental metals had close packed structures. With this determined the
concept of dislocations originally developed by Vito Volterra in 1907
became accepted, for instance being used to explain the ductility of
metals by G. I. Taylor in 1934.

The second was the advent of quantum mechanics. In 1924 Louis de
Broglie in his PhD thesis 'Recherches sur la théorie des quanta'
introduced his theory of electron waves. This rapidly became part of
what was called by Erwin Schrödinger 'undulatory mechanics', now
called the Schrödinger equation, wave mechanics or more commonly in
contemporary usage quantum mechanics. While it was not so easy to
solve the mathematics in the early days, fairly rapidly ideas such as
the chemical bond terminology of Linus Pauling as well as electronic
band structure concepts were developed.From this the concept of
nonmetals as "not-a-metal" originates. The original approach to
describe metals and nonmetals was a band-structure with delocalized
electrons (i.e. spread out in space). A nonmetal has a gap in the
energy levels of the electrons at the Fermi level. In contrast, a
metal would have at least one  partially occupied band at the Fermi
level; in a semiconductor or insulator there are no delocalized states
at the Fermi level, see for instance Ashcroft and Mermin. (A semimetal
is similar to a metal, with a slightly more complex band structure.)
These definitions are equivalent to stating that metals conduct
electricity at absolute zero, as suggested by Nevill Francis Mott, and
the equivalent definition at other temperatures is also commonly used
as in textbooks such as 'Chemistry of the Non-Metals' by Ralf Steudel
and work on metal-insulator transitions.

Originally this band structure interpretation was based upon a
single-electron approach with the Fermi level in the band gap as
illustrated in the Figure, not including a complete picture of the
many-body problem where both exchange and correlation terms matter, as
well as relativistic effects such as spin-orbit coupling. For
instance, the passivity of gold is typically associated with
relativistic terms. A key addition by Mott and Rudolf Peierls was that
these could not be ignored. For instance, nickel oxide would be a
metal if a single-electron approach was used, but in fact has quite a
large band gap. As of 2024 it is more common to use an approach based
upon density functional theory where the many-body terms are included.
Although accurate calculations remain a challenge, reasonable results
are now available in many cases.

It is common to nuance the early definition of Alan Herries Wilson and
Mott which was for a  zero temperature. As discussed by Peter Edwards
and colleagues, as well as Fumiko Yonezawa,it is important to consider
the temperatures at which both metals and nonmetals are used. Yonezawa
provides a general definition for both general temperatures and
conditions (such as standard temperature and pressure):



The precise meaning of semiconductor needs a little care. In terms of
the temperature dependence of their conductivity they are all
classified as insulators; the pure forms are intrinsic semiconductors.
When they are doped their conductivity continues to increase with
temperature, and can become substantial; hence the ambiguities with an
empirical categorisation using conductivity described earlier. Indeed,
some elements that are normally considered as insulators have been
exploited as semiconductors. For instance diamond, which has the
largest band gap of the elements that are solids under normal
conditions, has a number of semiconductor applications.

Band structure definitions of metals and nonmetals are widely used in
current research into materials, and apply both to single elements
such as insulating boron as well as compounds such as strontium
titanate. The characteristics associated with metals and nonmetals in
early work such as their appearance and mechanical properties are now
understood to be consequences of how the atoms and electrons are
arranged.


                 Comparison of selected properties
======================================================================
The two tables in this section list some of the properties of five
types of elements (noble gases, halogen nonmetals, unclassified
nonmetals, metalloids and, for comparison, metals) based on their most
stable forms at standard temperature and pressure. The dashed lines
around the columns for metalloids signify that the treatment of these
elements as a distinct type can vary depending on the author, or
classification scheme in use.


Physical properties by element type
=====================================
Physical properties are listed in loose order of ease of their
determination.

Property        Element type
Metals  Metalloids      Unc. nonmetals  Halogen nonmetals       Noble gases
|General physical appearance    lustrous        |lustrous                       colorless       |Form and
density solid  (Hg liquid)      solid   solid or gas    solid or gas  (bromine
liquid) gas     |often high density such as iron, lead, tungsten        |low to
moderately high density |low density    |rowspan=2| low density |low
density |some light metals including beryllium, magnesium, aluminium
|all lighter than iron  |hydrogen, nitrogen lighter than air    |helium,
neon lighter than air   Plasticity      mostly malleable and ductile    |often
brittle phosphorus, sulfur, selenium, brittle   iodine brittle  not
applicable      |Electrical conductivity        good    |{{indented
plainlist|indent=0.9em  * ◇ moderate: boron, silicon, germanium,
tellurium       * ◇ good: arsenic, antimony     }}    {{indented
plainlist|indent=0.9em  * ◇ poor: hydrogen, nitrogen, oxygen, sulfur  *
◇ moderate: phosphorus, selenium      * ◇ good: carbon        }}    {{indented
plainlist|indent=0.9em  * ◇ poor: fluorine, chlorine, bromine * ◇
moderate: I       }}    poor    |Electronic structure   metal (beryllium,
strontium, α-tin, ytterbium, bismuth are semimetals)   semimetal
(arsenic, antimony) or semiconductor            semiconductor () or insulator
insulator


Chemical properties by element type
=====================================
Chemical properties are listed from general characteristics to more
specific details.

Property        Element type
Metals  Metalloids       Unc. nonmetals Halogen nonmetals       Noble gases
|General chemical behavior              |weakly nonmetallic     moderately nonmetallic
strongly nonmetallic            |Oxides |basic; some amphoteric or acidic
|amphoteric or weakly acidic    |acidic or neutral      |acidic |metastable
XeO3 is acidic; stable XeO4 strongly so few glass formers       |all glass
formers |some glass formers     |no glass formers reported      |no glass
formers reported        |ionic, polymeric, layer, chain, and molecular
structures      |polymeric in structure |       |       |       |Compounds with metals  alloys
or intermetallic compounds      |tend to form alloys or intermetallic
compounds               mainly ionic    simple compounds at STP not known       |Ionization
energy (kJ mol−1) ‡       low to high     |moderate       moderate to high        high    high
to very high    376 to 1,007    762 to 947      941 to 1,402    1,008 to 1,681  1,037
to 2,372        average 643     average 833     average 1,152   average 1,270   average
1,589   |Electronegativity (Pauling) ‡      low to high     moderate        moderate to
high    high    high (radon) to very high       0.7 to 2.54     1.9 to 2.18     2.19 to
3.44    2.66 to 3.98    ca. 2.43 to 4.7 average 1.5     average 2.05    average
2.65    average 3.19    average 3.3

† Hydrogen can also form alloy-like hydrides
‡ The labels 'low', 'moderate', 'high', and 'very high' are
arbitrarily based on the value spans listed in the table


                              See also
======================================================================
* CHON (carbon, hydrogen, oxygen, nitrogen)
* List of nonmetal monographs
* Metallization pressure
* Nonmetal (astrophysics)
* Period 1 elements (hydrogen & helium)
* Properties of nonmetals (and metalloids) by group


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